Statistical optimization of process conditions for photocatalytic degradation of phenol with immobilization of nano TiO<Subscript>2</Subscript> on perlite granules

Response surface methodology (RSM) using D-optimal design was applied to optimization of photocatalytic degradation of phenol by new composite nano-catalyst (TiO₂/Perlite). Effects of seven factors (initial pH, initial phenol concentration, reaction temperature, UV irradiation time, UV light intensity, catalyst calcination temperature, and dosage of TiO₂/perlite) on phenol conversion efficiency were studied and optimized by using the statistical software MODDE 8.02. On statistical analysis of the results from the experimental studies, the optimum process conditions were as follows: initial pH, 10.7; initial phenol concentration, 0.5 mM; reaction temperature, 27 °C; UV irradiation time, 6.5 h; UV light intensity, 250 W; catalyst calcination temperature, 600 °C; and TiO₂/perlite dosage, 6 g/L. Analysis of variance (ANOVA) showed a high coefficient of determination (R²) of 91.8%.     

Tensile behaviour of patch-repaired CFRP laminates

The present study examines the tensile behaviour of composite structures repaired by bonding external patches. Various patches of different stacking sequences placed on both sides of the parent plate were considered. Damage development and the failure process of the repaired plates were analyzed and a parent plate fracture model has been proposed. Optimised patch repairs were calculated by finite element modelling. It was found that high stress concentration along the longitudinal edges of circular patches and/or at the transverse edges of the hole leads to early damage initiation in the parent plate. However, the position of damage initiation and the process of damage progression depend particularly on the properties of repair patches. In order to optimise patch repairs, finite element modelling was used and it was founded possible to attain over 90% of the strength of an unnotched specimen. The optimised patch design can be characterised by an optimal strength ratio R^*, which should be minimized when selecting repair parameters.     

Effect of micronisation and electromagnetic radiation on physical and mechanical properties of Canadian barley

The effect of micronisation (high‐intensity infrared heating) and microwave radiation of normal barley (NB), high‐amylose barley (HAB) and waxy barley (WB) on the physical and mechanical properties was studied. Samples were tempered to 42–45% moisture content and then subjected to infrared or microwave radiation to reduce the moisture content to approximately 10%. The grain surface temperature during radiation was maintained at 100 °C. The changes in physical and mechanical properties were compared with unprocessed samples. Thermal radiation increased slightly the volume of the kernels because of the diffusion of water vapour from inside to the outer surface. These changes resulted in a decrease in particle and bulk densities. Thermal radiation affected the Hunter colour values, as well. The mechanical properties including bio‐yield point, modulus of elasticity and breakage susceptibility were affected by micronisation and microwave heating.     

Combining continuous catalytic regenerative naphtha reformer with thermally coupled concept for improving the process yield

Advancements in the catalytic naphtha reforming process, as one of the main processes in petrochemical industry, contributed to development of continuous catalytic regenerative naphtha reformer units. Increasing the yield of aromatic and hydrogen as well as saving the energy in this process through the application of thermal coupling technique is a potentially interesting idea. This novel idea has been assessed in this paper. In the proposed configuration, continuous catalyst regeneration naphtha reforming process is coupled with hydrogenation of nitrobenzene in a two co-axial reactor separated by a solid wall, where the generated heat in nitrobenzene hydrogenation reaction transfers to naphtha reforming reaction medium through the surface of the tube. A steady-state, homogeneous, two-dimensional model is used to describe the performance of this configuration and a kinetic model including 32 pseudo-components with 84 reactions is considered for naphtha reforming reaction. After validating the model with the commercial data of a domestic plant, the obtained results of coupled reactor are compared by the conventional one. The obtained results show the superiority of CCR coupled reactor against the conventional one.     

High output impedance current-mode lowpass,bandpass and highpass filters using current controlled conveyors

Three new current-mode second-order filter configurations which employ one or two current controlled conveyors (CCCIIs) and three passive elements are presented. Each proposed filter can realize one of the bandpass, lowpass or highpass responses all at high impedance outputs. The proposed filters offer current-control of pole angular frequency ω_o without disturbing the parameter ω_o /Q. No component matching is required and all the passive and active sensitivities are low. PSPICE simulation results are given to confirm the theoretical analysis.     

Novel Voltage-Mode All-Pass Filter Based on Using DVCCs

In this paper, a novel design for realizing a voltage-mode (VM) all-pass filter utilizing two differential voltage current conveyors (DVCCs) is proposed. Also, the suggested filter uses a canonical number of passive elements (one grounded capacitor and one resistor) without requiring any element matching condition. The proposed filter has high input and low output impedances, which make it suitable for cascading. The effects of the nonidealities of the DVCCs on the proposed design are investigated. As an application, a quadrature oscillator is designed using the proposed VM all-pass filter and an integrator. The proposed filter and oscillator circuits are simulated using the SPICE simulation program to confirm the theory.